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   Copyright 2010 Peterson Publications,   Inc.
 Plastics Decorating Magazine
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 | Powder Coating - Recent Advancements for Industrial Plastics Applications
 by Scott Sabreen, The Sabreen Group, Inc.
 
 Technology Feature
 October-November2007
 
 
 
 The growth of powder coatings has been dramatic during the 
last decade with new applications continually being developed, including 
plastics. Innovations in processes and materials have opened previously 
unimaginable opportunities. Although environmental advantages have been a strong 
motivating factor for the conversion of liquid coatings to powder coatings, the 
bottom line for many companies is increased profitability. Leading manufacturers 
of powder coating technology foresee untapped potential in plastics applications 
including automotive, appliances, and many more.  The technology for coating products with dry powder rather 
than conventional liquids has been used since the 1950s. The powder used for the 
process is a mixture of finely ground particles of pigment, polymeric resin, and 
fillers. The powder can be sprayed electrostatically onto the substrate surface, 
or the substrate (product) can be dipped into a fluidized bed of suspended 
powder. During post heat curing, the particles flow and fuse into a strong 
adhering coating. The result is a high quality cosmetic finish with excellent 
durability.  Polyester TGIC coatings utilize the epoxy functional 
crosslinker TGIC (triglycidyl isocyanurate). Use of this low molecular weight, 
multifunctional crosslinker enables polyester TGIC formulations to contain 90 
percent or greater resin within the binder system. Weathering of polyester TGIC 
powders is comparable to polyester urethane coatings. Polyester TGIC coatings 
typically offer faster or lower temperature curing than polyurethanes. Unlike 
urethane coatings, TGICs maintain excellent mechanical properties at film builds 
above three mils with no outgassing. Additionally, TGIC coatings provide 
superior edge coverage when sharp edges are present.  The powder coating process involves finely ground particles 
of pigment and resin that are sprayed onto a substrate. Once the 
particles are applied, the part is cured, which causes a chemical reaction that 
bonds the powder to the work piece (substrate). The result is a uniform, high 
quality, and durable finish. This finish is more attractive than conventional 
methods due to the elimination of runs, drips, and uneven drying associated with 
liquid paint. The powder that does not adhere to the part is recovered and 
reused, generating a maximum efficiency of 98 percent material usage. This 
compares with a 30 to 80 percent utilization rate for most other spray coating 
processes. The most common technique used for powder coating is the 
electrostatic spray application process. The process involves a feed hopper and 
a spray gun, which incorporates the electrostatic charge of the particles. There 
are two types of spray guns, a corona and a tribo charged. The corona gun uses a 
voltage supply to charge the powder particles, while the tribo gun uses friction 
generated within the gun barrel. The corona technique negatively charges the 
particles. This generates electric fields, which causes uneven coating. The 
tribo gun positively charges the particles. As a result, there is no uneven 
coating, making it the optimal method for electrostatic spray application. Initially, the powder particles are stored in a large 
fluidized bed to keep them continuously suspended. The suspension of the 
particles prevents clogging in the pick-up tube that leads to the powder pump. 
The pump pulls the particles from the fluidized bed into the delivery tube. A 
second burst of air accelerates the particles, increasing the number of 
collisions with the Teflon walls and positively charging them (coatings). The 
tribostatic process is shown in Figure 2 (Tribostatic). The positively charged 
particles are sprayed out of the gun tip and adhered to the grounded work piece. 
This process can be seen in Figure 1 (Coatings). The work piece (substrate) is 
then placed in a furnace and cured at 300º F for 20 minutes (TGIC). The curing 
process causes a chemical reaction, bonding the powder coating and the 
substrate.  
	
		|  |  
		| Figure 1
 Electrostatic Spray Application System
 |  
 
	
		|  |  
		| Figure 2
 Tribostatic Gun Layout
 |  Of significant importance to plastics applications, UV 
powders with curing temperatures as low as 250°F have emerged. Such advancements 
now make it possible to apply powder coatings to some of the most widely used 
plastics, as either a secondary finishing process or during primary injection 
molding. For "In-mold" powder coating, the powder coating material is sprayed 
onto a heated mold cavity before the molding cycle begins. During the molding 
operation, the powder coating chemically bonds to the molding compound and 
produces a coated product that is chip- and impact-proof. Not unlike other technologies, powder coating has inherent 
advantages and disadvantages.  
	
		| 
			
				| Advantages | Disadvantages |  
				| No solvents, near zero VOCs | Thin coatings (< 1.0 mil) are difficult to 
				apply because of pin holes |  
				| Exhaust air from the coating booth can be 
				returned to the coating room, thus less oven air is exhausted to 
				the outside | Frequent color changes can entail extensive 
				downtime |  
				| Over-spray (up to 98 percent) can be 
				retrieved and reused | Storage and handling of powder requires 
				climate controls |  
				| No drying or flash time required so that 
				parts can be racked closer together | Exact color matching and color uniformity is 
				somewhat more difficult than with liquid coatings |  
				| Easily adapted to continuous automation 
				processes | Uniformity of coating thickness is sometimes 
				difficult to maintain |  
				| Operator-friendly | Cure temperatures required for some powders 
				are too high for temperature-sensitive parts |  
				| Thick coatings are easily achievable; film 
				thicknesses of 1.5 - 5.0 mils generally can be applied on cold 
				products | Conversion from liquid coating processes is 
				expensive |  
				| High volume production rates | Inside corners can have low film thickness – 
				"Faraday Cage Effect" |  
				| Easy clean-up and maintenance | Some difficulty with preparing certain types 
				of metallic appearances; texture finishes are limited, unlike 
				wet texturing |  
				| Powder Coating does not drip or sag; the 
				process is more robust than Liquid Coating | Repairing blemishes in powder coating films 
				can be difficult; matching liquid coating for repairs is not 
				normally viable |  |  |  Recent breakthroughs in powder coating technology have 
approached the mar performance usually associated with porcelain enamels, as 
measured by commonly used industry tests. This provides significant value to 
customers. The final properties of the powder coatings often are superior to 
liquid coating systems. The reasons for the fast growth of this technology is 
that powder coatings maximize production, cut costs, improve efficiencies, and 
offer maximum compliance with increasingly stringent environmental regulations. 
The future for broad scope powder coating on plastics is bright. 
 References: SpecialChem – Coatings & Inks. Coatings.de. 26 April 2004. Vincentz Network. 08 April 
	2004.  What Are TGIC Powder Coatings? 26 April 2004. Caswell. 15 
	April 2004.  Tribostatic Powder Spray Systems. 26 April 2004. Nordson 
	Corporation. Scott R. Sabreen is founder and president of The Sabreen 
Group, Inc. (TSG). TSG is a global engineering company specializing in secondary 
plastics manufacturing processes – surface pretreatments, bonding, decorating 
and finishing, laser marking, and product security. For more information, call 
toll free (888) SABREEN or visit www.sabreen.com  and 
www.plasticslasermarking.com.  
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