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Plastics Decorating Magazine
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Powder Coating - Recent Advancements for Industrial Plastics Applications
by Scott Sabreen, The Sabreen Group, Inc.
Technology Feature
October-November2007
The growth of powder coatings has been dramatic during the
last decade with new applications continually being developed, including
plastics. Innovations in processes and materials have opened previously
unimaginable opportunities. Although environmental advantages have been a strong
motivating factor for the conversion of liquid coatings to powder coatings, the
bottom line for many companies is increased profitability. Leading manufacturers
of powder coating technology foresee untapped potential in plastics applications
including automotive, appliances, and many more.
The technology for coating products with dry powder rather
than conventional liquids has been used since the 1950s. The powder used for the
process is a mixture of finely ground particles of pigment, polymeric resin, and
fillers. The powder can be sprayed electrostatically onto the substrate surface,
or the substrate (product) can be dipped into a fluidized bed of suspended
powder. During post heat curing, the particles flow and fuse into a strong
adhering coating. The result is a high quality cosmetic finish with excellent
durability.
Polyester TGIC coatings utilize the epoxy functional
crosslinker TGIC (triglycidyl isocyanurate). Use of this low molecular weight,
multifunctional crosslinker enables polyester TGIC formulations to contain 90
percent or greater resin within the binder system. Weathering of polyester TGIC
powders is comparable to polyester urethane coatings. Polyester TGIC coatings
typically offer faster or lower temperature curing than polyurethanes. Unlike
urethane coatings, TGICs maintain excellent mechanical properties at film builds
above three mils with no outgassing. Additionally, TGIC coatings provide
superior edge coverage when sharp edges are present.
The powder coating process involves finely ground particles
of pigment and resin that are sprayed onto a substrate. Once the
particles are applied, the part is cured, which causes a chemical reaction that
bonds the powder to the work piece (substrate). The result is a uniform, high
quality, and durable finish. This finish is more attractive than conventional
methods due to the elimination of runs, drips, and uneven drying associated with
liquid paint. The powder that does not adhere to the part is recovered and
reused, generating a maximum efficiency of 98 percent material usage. This
compares with a 30 to 80 percent utilization rate for most other spray coating
processes.
The most common technique used for powder coating is the
electrostatic spray application process. The process involves a feed hopper and
a spray gun, which incorporates the electrostatic charge of the particles. There
are two types of spray guns, a corona and a tribo charged. The corona gun uses a
voltage supply to charge the powder particles, while the tribo gun uses friction
generated within the gun barrel. The corona technique negatively charges the
particles. This generates electric fields, which causes uneven coating. The
tribo gun positively charges the particles. As a result, there is no uneven
coating, making it the optimal method for electrostatic spray application.
Initially, the powder particles are stored in a large
fluidized bed to keep them continuously suspended. The suspension of the
particles prevents clogging in the pick-up tube that leads to the powder pump.
The pump pulls the particles from the fluidized bed into the delivery tube. A
second burst of air accelerates the particles, increasing the number of
collisions with the Teflon walls and positively charging them (coatings). The
tribostatic process is shown in Figure 2 (Tribostatic). The positively charged
particles are sprayed out of the gun tip and adhered to the grounded work piece.
This process can be seen in Figure 1 (Coatings). The work piece (substrate) is
then placed in a furnace and cured at 300º F for 20 minutes (TGIC). The curing
process causes a chemical reaction, bonding the powder coating and the
substrate.
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Figure 1
Electrostatic Spray Application System |
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Figure 2
Tribostatic Gun Layout |
Of significant importance to plastics applications, UV
powders with curing temperatures as low as 250°F have emerged. Such advancements
now make it possible to apply powder coatings to some of the most widely used
plastics, as either a secondary finishing process or during primary injection
molding. For "In-mold" powder coating, the powder coating material is sprayed
onto a heated mold cavity before the molding cycle begins. During the molding
operation, the powder coating chemically bonds to the molding compound and
produces a coated product that is chip- and impact-proof.
Not unlike other technologies, powder coating has inherent
advantages and disadvantages.
Advantages
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Disadvantages
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No solvents, near zero VOCs
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Thin coatings (< 1.0 mil) are difficult to
apply because of pin holes
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Exhaust air from the coating booth can be
returned to the coating room, thus less oven air is exhausted to
the outside
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Frequent color changes can entail extensive
downtime
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Over-spray (up to 98 percent) can be
retrieved and reused
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Storage and handling of powder requires
climate controls
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No drying or flash time required so that
parts can be racked closer together
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Exact color matching and color uniformity is
somewhat more difficult than with liquid coatings
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Easily adapted to continuous automation
processes
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Uniformity of coating thickness is sometimes
difficult to maintain
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Operator-friendly
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Cure temperatures required for some powders
are too high for temperature-sensitive parts
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Thick coatings are easily achievable; film
thicknesses of 1.5 - 5.0 mils generally can be applied on cold
products
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Conversion from liquid coating processes is
expensive
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High volume production rates
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Inside corners can have low film thickness –
"Faraday Cage Effect"
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Easy clean-up and maintenance
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Some difficulty with preparing certain types
of metallic appearances; texture finishes are limited, unlike
wet texturing
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Powder Coating does not drip or sag; the
process is more robust than Liquid Coating
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Repairing blemishes in powder coating films
can be difficult; matching liquid coating for repairs is not
normally viable
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Recent breakthroughs in powder coating technology have
approached the mar performance usually associated with porcelain enamels, as
measured by commonly used industry tests. This provides significant value to
customers. The final properties of the powder coatings often are superior to
liquid coating systems. The reasons for the fast growth of this technology is
that powder coatings maximize production, cut costs, improve efficiencies, and
offer maximum compliance with increasingly stringent environmental regulations.
The future for broad scope powder coating on plastics is bright.
References:
SpecialChem – Coatings & Inks.
Coatings.de. 26 April 2004. Vincentz Network. 08 April
2004.
What Are TGIC Powder Coatings? 26 April 2004. Caswell. 15
April 2004.
Tribostatic Powder Spray Systems. 26 April 2004. Nordson
Corporation.
Scott R. Sabreen is founder and president of The Sabreen
Group, Inc. (TSG). TSG is a global engineering company specializing in secondary
plastics manufacturing processes – surface pretreatments, bonding, decorating
and finishing, laser marking, and product security. For more information, call
toll free (888) SABREEN or visit www.sabreen.com and
www.plasticslasermarking.com.
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